A research team from the Institute of Materials Science, Vietnam Academy of Science and Technology (VAST)—including Le Thi Hai Ninh, Pham Thi Hai Thinh, Nguyen Duc Nui, and Duong Van Nam—has carried out a study on phosphorus recovery from natural rubber processing wastewater using the struvite precipitation method.
The objective of this work is to examine the feasibility of recovering phosphorus from natural rubber processing wastewater through struvite precipitation. This technology not only supports wastewater treatment but also enables the production of fertilizer from the recovered phosphorus, contributing to environmental protection and supplying nutrients for agriculture.
Phosphorus is a non-renewable element essential for plant growth. However, global natural phosphorus reserves are rapidly depleting. Recovering phosphorus from wastewater provides a sustainable solution for fertilizer production, pollution reduction, and the conservation of natural resources.
From wastewater to resource: Turning phosphorus into struvite
Struvite (MgNH₄PO₄·6H₂O) precipitation is one of the most effective techniques for recovering phosphorus from wastewater. The process occurs when magnesium (Mg²⁺), ammonium (NH₄⁺), and phosphate (PO₄³⁻) ions combine in solution to form struvite crystals. The resulting product not only removes phosphorus from wastewater but can also be used directly as a fertilizer.
The experiments were conducted using wastewater samples from natural rubber processing, which is characterized by extremely high pollutant loads, including phosphate concentrations of 420–450 mg/L. This creates significant potential for phosphorus recovery—estimated at approximately 157,625 tonnes in 2024.
Struvite shows promise: Efficiency, conditions, and key findings
Natural rubber processing wastewater contains a wide range of pollutants, with phosphorus accounting for a substantial portion. Phosphate levels can reach 420–450 mg/L, posing severe environmental risks if untreated. The study demonstrates that struvite precipitation is highly effective in recovering phosphorus from this wastewater stream.
The estimated recoverable phosphorus amount—157,625 tonnes in 2024—represents a notable resource. This recovered phosphorus could be used as fertilizer, providing an important supplementary input for Vietnam’s agricultural sector.
A new opportunity for the rubber industry’s circular future
Phosphorus recovery from natural rubber processing wastewater not only mitigates environmental pollution but also helps address fertilizer shortages in Vietnam. The recovered phosphorus can serve as a sustainable fertilizer source, reducing reliance on imported chemical fertilizers.
In addition, the approach helps lower wastewater treatment costs for rubber processing plants while generating a valuable product without creating additional pollution.
The work by Le Thi Hai Ninh, Pham Thi Hai Thinh, Nguyen Duc Nui, and Duong Van Nam demonstrates a sustainable pathway for managing wastewater from the natural rubber processing industry. Struvite precipitation offers a dual benefit: recovering phosphorus for fertilizer use and supporting environmental protection—thereby contributing to a more resilient and sustainable agricultural sector in Vietnam.